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Lumisterol is a compound that is part of the vitamin D family of steroid compounds. It is the (9β,10α) stereoisomer of ergosterol and was produced as a photochemical by-product in the preparation of vitamin D1, which was a mixture of vitamin D2 and lumisterol.[1][2] Vitamin D2 can be formed from lumisterol by an electrocyclic ring opening and subsequent sigmatropic [1,7] hydride shift.

Lumisterol has an analog based on 7-dehydrocholesterol, known as lumisterol 3.[3]

References

  1. ^ Dewick, Paul M. (2002). Medicinal Natural Products. A Biosynthetic Approach (PDF) (Second ed.). New York: John Wiley & Sons. p. 259. ISBN 0-471-49640-5.
  2. ^ Friedmann, Ernst (1989). Neurath, Hans (ed.). Vitamin D. Perspectives in Biochemistry. Vol. 1. Washington, DC: American Chemical Society. ISBN 978-0-8412-1621-1.
  3. ^ National Center for Biotechnology Information. "Lumisterol 3 (CID=111049)". PubChem Compound Database. Retrieved 10 April 2018.


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