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Rubidium pertechnetate is a pertechnetate of rubidium, with the chemical formula RbTcO4.
Preparation
Rubidium pertechnetate can be prepared by reacting rubidium carbonate with ammonium pertechnetate:[2]
Rb2CO3 + 2 NH4TcO4 → 2 RbTcO4 + (NH4)2CO3
Properties
Rubidium pertechnetate crystallizes in the tetragonal crystal system, with space group I41/a, and lattice parameters a = 576.2 pm and c = 1354.3 pm. In its structure, the Tc–O bond length is 172.3 pm, O–Tc–O bond angle is 108.34°.[2]
References
- ^ a b Klaus Schwochau (November 2008). Technetium: Chemistry and Radiopharmaceutical Applications. John Wiley & Sons. p. 129. ISBN 978-3527613373.
- ^ a b Jamie Weaver, Chuck Z. Soderquist, Nancy M. Washton, Andrew S. Lipton, Paul L. Gassman, Wayne W. Lukens, Albert A. Kruger, Nathalie A. Wall, John S. McCloy (February 2017). "Chemical Trends in Solid Alkali Pertechnetates". Inorganic Chemistry. 56 (5). Inorg. Chem.: 2533–2544. doi:10.1021/acs.inorgchem.6b02694. PMID 28221786.
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