Beryllium borohydride is an inorganic compound with the chemical formula Be[BH4]2.[2]

Preparation

Beryllium borohydride is formed by the reaction of beryllium hydride with diborane in an ether solution.

It can also be formed by the reaction of beryllium chloride and lithium borohydride in a sealed tube at 120 °C:[2]

BeCl2 + 2 Li[BH4] → Be[BH4]2 + 2 LiCl

Structure

The chemical formula of beryllium borohydride can be written as Be2+([BH4]−)2. The crystal structure is made up of a helical polymer of BH4Be and BH4 structure units.[2][3] The borohydride ions, [BH4]−, adopt a tetrahedral geometry.[3] Beryllium is 6-coordinate and adopts a distorted trigonal prismatic geometry.[2]

Application

The purest beryllium hydride is obtained by the reaction of triphenylphosphine, PPh3, with beryllium borohydride, Be[BH4]2 at 180 °C:[2]

Be[BH4]2 + 2 PPh3 → 2 Ph3P+−−BH3 + BeH2

References

  1. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0054". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ a b c d e Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 115–116. ISBN 978-0-08-037941-8.
  3. ^ a b Marynick, Dennis S.; Lipscomb, William N. (1 April 1972). "Crystal structure of beryllium borohydride". Inorg. Chem. 11 (4): 820–823. doi:10.1021/ic50110a033.