Palladium(II) fluoride, also known as palladium difluoride, is the chemical compound of palladium and fluorine with the formula PdF2.
Synthesis
PdF2 is prepared by refluxing palladium(II,IV) fluoride, PdII[PdIVF6], with selenium tetrafluoride, SeF4.
- Pd[PdF6] + SeF4 → 2PdF2 + SeF6
Structure and paramagnetism
Like its lighter congener nickel(II) fluoride, PdF2 adopts a rutile-type crystal structure,[2][3] containing octahedrally coordinated palladium, which has the electronic configuration t6
2g e2
g. This configuration causes PdF2 to be paramagnetic[4] due to two unpaired electrons, one in each eg-symmetry orbital of palladium.
Applications
Palladium fluoride is an insoluble powder used in infrared optical sensors,[5] and in situations where reactivity to oxygen makes palladium oxide unsuitable.
See also
References
- ^ a b c CRC Handbook, 89th edition
- ^ Bachmann, B.; Müller, B. G. (1993). "Einkristalluntersuchungen an Fluoroperowskiten MPdF3 (M = Rb, K) und PdF2". Z. Anorg. Allg. Chem. 619 (2): 387–391. doi:10.1002/zaac.19936190225.
- ^ Holleman, A. F.; Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Web: Academic Press. p. 1515. ISBN 9780123526519. Retrieved 30 May 2020.
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.
- ^ "American_Elements.com".
Recent Comments